KEYWORDS
TOPICS
ABSTRACT
Investigation of exhaust emissions and ammonia flow behavior in the exhaust system incorporating with Selective Catalytic Reduction (SCR) unit is discussed. An aftertreatment system is designed to work without additional urea injection to improve feasible temperature of operating and reduce size. This study is focused on obtaining optimal parameters for catalysis using gaseus ammonia as reducing agent. Its effectiveness is considered as a function of basic parameters of exhaust gases mixture and SCR material characteristics. A 3D geometry of SCR with porous volume has been simulated using Ansys Fluent. Moreover, a 1D model of ammonia dual-fuel CI engine has been obtained. Results were focused on obtaining local temperature, velocity, and exhaust gases composition to predict optimal probes placement, pipes insulation parameters, and characteristic dimensions.
FUNDING
This work was funded by Norway and Poland contract (Contract NO. NOR/POLNOR/ACTIVATE/0046/2019-00) in ACTIVATE Project. Further information: https://ammoniaengine.org
 
REFERENCES (18)
1.
GRANNELL, S.M., ASSANIS, D.N., BOHAC, S.V. et al. The fuel mix limits and efficiency of a stoichiometric, ammonia, and gasoline dual fuelled spark ignition engine. Journal of engineering for gas turbines and power. 2008, 130(4). https://doi.org/10.1115/1.2898....
 
2.
REITER, A.J., KONG, S.C. Combustion and emissions characteristics of compression-ignition engine using dual ammonia-diesel fuel. Fuel. 2011, 90(1), 87-97. https://doi.org/10.1016/j.fuel....
 
3.
REITER, A.J., KONG, S.C. Demonstration of compression-ignition engine combustion using ammonia in reducing greenhouse gas emissions. Energy & Fuels. 2008, 22(5), 2963-2971. https://doi.org/10.1021/ef8001....
 
4.
SALEK, F., BABAIE, M., SHAKERI, A. et al. Numerical study of engine performance and emissions for port injection of ammonia into a gasoline\ethanol dual-fuel spark ignition engine. Applied Sciences. 2021, 11(4), 1441. https://doi.org/10.3390/app110....
 
5.
VALERA, A. et al. Review on ammonia as a potential fuel: from synthesis to economics. Energy Fuels. 2021, 35, 6964-7029. https://doi.org/10.1021/acs.en....
 
6.
NAKAJIMA, F., HAMADA, I. The state-of-the-art technology of NOx control. Catalysis Today. 1996, 29, 109-115. https://doi.org/10.1016/0920-5....
 
7.
SOO-JIN, J., WOO-SEUNG, K. A numerical approach to investigate transient thermal and conversion characteristics of automotive catalytic converter, advanced converter concepts for emission control. SAE Technical Paper 980881. 1998. https://doi.org/10.4271/980881.
 
8.
HUANG, H., CHEN, Y., Li, Z. et al. Analysis of deposit formation mechanism and structure optimization in urea-SCR system of diesel engine. Fuel. 2020, 265, 116941. https://doi.org/10.1016/j.fuel....
 
9.
KOEBEL, M., ELSENER, M., KLEEMANN, M. Urea-SCR: a promising technique to reduce NOx emissions from automotive diesel engines. Catalysis Today. 2000, 59(3-4), 335-345. https://doi.org/10.1016/S0920-....
 
10.
ROPPERTZ, A., FÜGER, S., KURETI, S. Investigation of urea-SCR at low temperatures. Topics in Catalysis. 2017, 60, 199-203. https://doi.org/10.1007/s11244....
 
11.
DAMMA, D., ETTIREDDY P.R., REDDY, B.M. et al. A review of low temperature NH3-SCR for removal of NOx. Catalysts, 2019, 9(4), 349. https://doi.org/10.3390/catal9....
 
12.
DUMESIC, J.A., TOPSOE, N.-Y., CHEN, Y. et al. Kinetics of selective catalytic reduction of nitric oxide by ammonia over vanadia/titania. Journal of Catalysis. 1996, 163, 409-417. https://doi.org/10.1006/jcat.1....
 
13.
ZHU, Y., ZHOU, S., FENG, Y. et al. Influence of NH4NO3 formation on the NOx reduction pathways over vanadium-based catalyst under diesel exhaust conditions. Russian Journal of Physical Chemistry A. 2018, 92, 1473-1480. https://doi.org/10.1134/S00360....
 
14.
NOVA, I., CIARDELLI, C., TRONCONI, E. Unifying redox kinetics for standard and fast NH3‐SCR over a V2O5‐WO3/TiO2 catalyst. AIChE Journal. 2009, 55(6), 1514-1529. https://doi.org/10.1002/aic.11....
 
15.
NOVA, I. COLOMBO, M., TRONCONI, E. Kinetic modeling of dynamic aspects of the standard NH3-SCR reaction over V2O5-WO3/TiO2 and Fe-zeolite commercial catalysts for the aftertreatment of diesel engines exhausts. Oil & Gas Science and Technology – Revue de l IFP. 2011, 66(4), 681-691. https://doi.org/10.2516/ogst/2....
 
16.
YAO, J. ZHONG, Z., ZHU, L. Porous medium model in computational fluid dynamics simulation of a honeycombed SCR DeNOx catalyst. Chemical Engineering & Technology. 2015, 38(2), 283-290. https://doi.org/10.1002/ceat.2....
 
17.
KURZYDYM, D., KLIMANEK, A., ŻMUDKA, Z. Experimental and numerical analysis of flow through catalytic converters for original part and WALKER’s replacement using reverse engineering and CFD. IOP Conferences Series: Materials Science and Engineering. 2018, 421, 042044. https://doi.org/10.1088/1757-8....
 
18.
KURZYDYM, D., KLIMANEK, A., ŻMUDKA, Z. Experimental research and CFD analysis of flow parameters in a SCR system for the original part and WALKER’s replacement. Combustion Engines. 2019, 179(4), 12-19. https://doi.org/10.19206/CE-20....
 
 
CITATIONS (1):
1.
Experimental verification of changes in the control map of a diesel engine operation due to fuel consumption
Zbigniew Jan Sroka, Rafał Heda
Combustion Engines
 
eISSN:2658-1442
ISSN:2300-9896
Journals System - logo
Scroll to top