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Ammonia as an alternative fuel to internal combustion engines
1
Performance Testing Department, OIL and GAS INSTITUTE National Reseach Institute, Poland
Submission date: 2024-12-16
Final revision date: 2025-01-19
Acceptance date: 2025-01-19
Online publication date: 2025-02-07
Corresponding author
Zbigniew Stępień
Performance Testing Department, OIL and GAS INSTITUTE National Reseach Institute, Lubicz 25A, 31-503, Kraków, Poland
Performance Testing Department, OIL and GAS INSTITUTE National Reseach Institute, Lubicz 25A, 31-503, Kraków, Poland
KEYWORDS
TOPICS
ABSTRACT
The article presents a broad review of the current state of knowledge in the potential of using ammo-nia as a fuel for internal combustion engines. A critical analysis of the physicochemical and functional properties of ammonia was carried out in the context of using it as a fuel for internal combustion en-gines. Challenges related to the problems of creating a mixture and the combustion process of ammonia in both SI and CI engines were described. It was indicated that using an admixture of small amounts of fuels to ammonia to act as combustion promoters was necessary. Attention was drawn to the problems related to the exhaust emissions that occur when using ammonia or ammonia with an admixture of other fuels to power engines. The issue of the adverse effect of ammonia combustion products and ammonia itself on the lubricating engine oil was also discussed. The need to develop dedicated lubricating oils for internal combustion engines fueled with ammonia was explained..
REFERENCES (82)
1.
Agocs A, Rappo M, Obrecht N, Schneidhofer C, Frauscher M, Besser C. The impact of ammonia fuel on marine engine lubrication: an artificial lubricant ageing approach. Lubricants. 2023;11:165. https://doi.org/10.3390/lubric....
2.
Ali Brohi E. Ammonia as fuel for internal combustion engines? An evaluation of the feasibility of using nitrogen-based fuels in ICE. 2014. Master’s Thesis 2014:55. Department of Applied Mechanics, Division of Combustion, Chalmers University of Technology, Gothenburg, Sweden.
3.
Alnajideen M, Shi H, Northrop W, Emberson D, Kane S, Czyżewski P et al. Ammonia combustion and emissions in practical applications: a review. Carbon Neutrality. 2024;3(13):3-13. https://doi.org/10.1007/s43979....
4.
Amoresa JMG, Escribanoa VS, Ramisb G, Buscab G. An FT-IR study of ammonia adsorption and oxidation over anatase-supported metal oxides. Appl Catal B-Environ. 1997;13(1):45-58. https://doi.org/10.1016/S0926-....
5.
Aung KT, Hassan MI, Faeth GM. Flame stretch interactions of laminar premixed hydrogen/air flames at normal temperature and pressure. Combust Flame. 1997;109(1-2):1-24. https://doi.org/10.1016/S0010-....
6.
Bayraktar H, Durgun O. Investigating the effects of LPG on spark ignition engine combustion and performance. Energ Convers Manage. 2005;46(13-14):2317-2333. https://doi.org/10.1016/j.enco....
7.
Besser C, Agocs A, Ronai B, Ristic A, Repka M, Jankes E et al. Generation of engine oils with defined degree of degradation by means of a large scale artificial alteration method. Tribol Int. 2019;132:39-49. https://doi.org/10.1016/j.trib....
8.
Besser C, Schneidhofer C, Dörr N, Novotny-Farkas F, Allmaier G. Investigation of long-term engine oil performance using lab-based artificial ageing illustrated by the impact of ethanol as fuel component. Tribol Int. 2012;46(1):174-182. https://doi.org/10.1016/j.trib....
9.
Boretti A. Novel dual fuel diesel-ammonia combustion system in advanced TDI engines. Int J Hydrogen Energ. 2017;42(10):7071-7076. https://doi.org/10.1016/j.ijhy....
10.
Braun A, Gierenz N, Braun S, Kubach H, Bernhardt S, Prehn S et al. Aspects of ammonia as green fuel for propulsion systems of inland water vessels. Energy Technol. 2301648. https://doi.org/10.1002/ente.2....
11.
Chiong M-C, Chong CT, Ng J-H, Mashruk S, Chong WWF, Samiran NA et al. Advancements of combustion technologies in the ammonia-fuelled engines. Energ Convers Manage. 2021;244:114460. https://doi.org/10.1016/j.enco....
12.
Cooper JR, Crookes RJ, Mozafari A, Rose JW. Ammonia as fuel for IC engine. International Conference on Environmental Pollution. 1991;1:242-249. Lisbon, Portugal.
13.
Cracknell R, Head B, Remmert S, Wu Y, Prakash A, Luebbers M. Laminar burning velocity as a fuel characteristic: impact on vehicle performance. Internal Combustion Engines: Performance, Fuel Economy and Emissions. 2013: 149-156. https://doi.org/10.1533/978178....
14.
Dimitriou P, Javaid R. A review of ammonia as a compression ignition engine fuel. Int J Hydrogen Energ. 2020;45(11):7098-7118. https://doi.org/10.1016/j.ijhy....
15.
Dinesh MH, Pandey JK, Kumar GN. Study of performance, combustion, and NOx emission behavior of an SI engine fuelled with ammonia/hydrogen blends at various compression ratio. Int J Hydrogen Energ. 2022;47(60):25391-25403. https://doi.org/10.1016/j.ijhy....
16.
EEA, Special report 01/2024: Reducing carbon dioxide emissions from passenger cars – finally picking up pace, but challenges on the road ahead. https://www.eca.europa.eu/en/p....
17.
Elishav O, Lis BM, Miller EM, Arent DJ, Valera-Medina A, Dana AG et al. Progress and prospective of nitrogen-based alternative fuels. Chem Rev. 2020;120(12):5352-5436. https://doi.org/10.1021/acs.ch....
18.
Erdemir D, Dincer I. A perspective on the use of ammonia as a clean fuel: challenges and solutions. Int J Energ Res. 2021;45:4827-4834. https://doi.org/10.1002/er.623....
19.
Feng Y, Zhu J, Mao Y, Raza M, Qian Y, Yu L et al. Low-temperature auto-ignition characteristics of NH3/diesel binary fuel: ignition delay time measurement and kinetic analysis. Fuel. 2020;281:118761. https://doi.org/10.1016/j.fuel....
20.
Frigo S, Gentili R. Analysis of the behaviour of a 4-stroke SI engine fuelled with ammonia and hydrogen. Int J Hydrogen Energ. 2013;38(3):1607-1615. https://doi.org/10.1016/j.ijhy....
21.
Ghosh RS, Dhillon PS, Harold MP, Wang D. Kinetics of NH3 oxidation on Pt/Al2O3: rate enhancement and NH3 inhibition. Chem Eng J. 2021;417:128273. https://doi.org/10.1016/j.cej.....
22.
Grannell SM, Assanis DN, Bohac SV, Gillespie DE. The fuel mix limits and efficiency of a stoichiometric, ammonia, and gasoline dual fueled spark ignition engine. J Eng Gas Turb Power. 2008;130(4):042802. https://doi.org/10.1115/1.2898....
23.
Grannell SM, Assanis DN, Gillespie DE, Bohac SV. Exhaust emissions from a stoichiometric, ammonia and gasoline dual fueled spark ignition engine. ASME 2009 Internal Combustion Engine Division Spring Technical Conference ICES2009-76131. https://doi.org/10.1115/ICES20....
24.
Gray JT, Dimitroff E, Meckel NT, Quillian RD. Ammonia fuel – engine compatibility and combustion. SAE Technical Paper. 660156. 1966. https://doi.org/10.4271/660156.
25.
Gross CW, Kong S-C. Performance characteristics of a compression-ignition engine using direct-injection ammonia–DME mixtures. Fuel. 2013;103:1069-1079. https://doi.org/10.1016/j.fuel....
26.
Han L, LI J, Zhao D, Xi Y, Gu X, Wang N. Effect analysis on energy conversion enhancement and NOx emission reduction of ammonia/hydrogen fuelled wavy micro-combustor for microthermophotovoltaic application. Fuel. 2021;289:119755. https://doi.org/10.1016/j.fuel....
27.
He X, Shu B, Nascimento D, Moshammer K, Costa M, Fernandes RX. Auto-ignition kinetics of ammonia and ammonia/hydrogen mixtures at intermediate temperatures and high pressures. Combust Flame. 2019;206:189-200. https://doi.org/10.1016/j.comb....
28.
Herbinet O, Bartocci P, Grinberg Dana A. On the use of ammonia as a fuel – a perspective. Fuel Communications. 2022;11:100064. https://cnrs.hal.science/hal-0....
29.
Ichikawa A, Hayakawa A, Kitagawa Y, Somarathne KD, Kudo T, Kobayashi H. Laminar burning velocity and Markstein length of ammonia/hydrogen/air premixed flames at elevated pressures. Int J Hydrogen Energ. 2015;40(30):9570-9578. https://doi.org/10.1016/j.fuel....
30.
Ichimura R, Hadi K, Hashimoto N, Hayakawa A, Kobayashi H, Fujita O. Extinction limits of an ammonia/air flame propagating in a turbulent field. Fuel. 2019;246:178-186. https://doi.org/10.1016/j.fuel....
31.
Klüssmann J, Schramm J, Ekknud L.R, Ivarsson A. Ammonia application in IC engines. 2020. Advanced Motor Fuels. Special Report. A Report from the Advanced Motor Fuels Technology Collaboration Programme. https://iea-amf.org/app/webroo....
32.
Kobayashi H, Hayakawa A, Somarathne KD, Okafor EC. Science and technology of ammonia combustion. P Combust Inst. 2019;37:109-133. https://doi.org/10.1016/j.proc....
33.
Kumar P, Meyer TR. Experimental and modeling study of chemical-kinetics mechanisms for H2-NH3-air mixtures in laminar premixed jet flames. Fuel. 2013;108:166-176. https://doi.org/10.1016/j.fuel....
34.
Kumar L, Sleiti AK. Systematic review on ammonia as a sustainable fuel for combustion. Renew Sust Energ Rev. 2024;202:114699. https://doi.org/10.1016/j.rser....
35.
Lamas Galdo MI, Castro-Santos L, Rodriguez Vidal CG. Numerical analysis of NOx reduction using ammonia injection and comparison with water injection. J Mar Sci Eng. 2020;8(2):109. https://doi.org/10.3390/jmse80....
36.
Lhuillier C, Brequigny P, Contino F, Mounaïm-Rousselle C. Experimental study on ammonia/hydrogen/air combustion in spark ignition engine conditions. Fuel. 2020;269:117448. https://doi.org/10.1016/j.fuel....
37.
Lhuillier C, Brequigny P, Contino F, Rousselle C. Performance and emissions of an ammonia-fueled SI engine with hydrogen enrichment. SAE Technical Paper. 2019-24-0137. 2019. https://doi.org/10.4271/2019-2....
38.
Liebherr. Liebherr introduces H2 direct injection for heavy-duty combustion engines. https://www.liebherr.com/en-us....
39.
Mathieu O, Petersen EL. Experimental and modeling study on the high temperature oxidation of ammonia and related NOx chemistry. Combust Flame. 2015;162(3):554-570. https://doi.org/10.1016/j.comb....
40.
Mercier A, Mounaïm-Rousselle C, Brequigny P, Bouriot J, Dumand C. Improvement of SI engine combustion with ammonia as fuel: effect of ammonia dissociation prior to combustion. Fuel Communication. 2022,11:100058. https://doi.org/10.1016/j.jfue....
41.
Mørch CS, Bjerre A, Gøttrup MP, Sorenson SC, Schramm J. Ammonia/hydrogen mixtures in an SI-engine: engine performance and analysis of a proposed fuel system. Fuel. 2011;90(2):854-864. https://doi.org/10.1016/j.fuel....
42.
Mounaïm-Rousselle C. Ammonia as zero-carbon fuel for internal combustion engine: “where are we today?”. ICE2021. 15th International Conference on Engines & Vehicles. September 12-16, 2021, Capri Naples, Italy.
43.
Mounaïm-Rousselle C, Bréquigny P, Valera-Medina A, Boulet E, Emberson D, Løvås T. Ammonia as fuel for transportation to mitigate zero carbon impact. Energy, Environment, and Sustainability. 2022:257-279. https://doi.org/10.1007/978-98....
44.
Mounaïm-Rousselle C, Mercier A, Brequigny P, Dumand C, Bouriot J, Houill´e S. Performance of ammonia fuel in a spark assisted compression ignition engine. Int J Engine Res. 2021;23(5):781-792. https://doi.org/10.1177/146808....
45.
Nadimi E, Przybyła G, Lewandowski MT, Adamczyk W. Effects of ammonia on combustion, emissions, and performance of the ammonia/diesel dual-fuel compression ignition engine. J Energy Inst. 2023;107;101158. https://doi.org/10.1016/j.joei....
46.
Obrecht O, Griffaton B, Rappo M. Lubricant performance and reliability of ammonia fueled internal combustion engines. SAE Technical Paper. 2023-32-0104. 2023. https://doi.org/10.4271/2023-3....
47.
Pacheco GP, Rocha RC, Franco MC, Mendes MAA, Fernandes EC, Coelho PJ al. Experimental and kinetic investigation of stoichiometric to rich NH3/H2/air flames in a swirl and bluff-body stabilized burner. Energy Fuels. 2021;35(9):7201-7216. https://doi.org/10.1021/acs.en....
48.
Partington JR, Prince AJ. The explosion of ammonia with electrolytic gas and oxygen. J Chem Soc Trans. 1924;125:2018-2025. https://doi.org/10.1039/CT9242....
49.
Pearsall TJ, Garabedian CG. Combustion of anhydrous ammonia in diesel engines, SAE Technical Paper. 670947. 1967. https://doi.org/10.4271/670947.
50.
Qi G. Selective catalytic oxidation (SCO) of ammonia to nitrogen over Fe-exchanged zeolites prepared by sublimation of FeCl3. J Catal. 2004;226(1):120-128. https://doi.org/10.1016/j.jcat....
51.
Qi Y, Liu W, Liu S, Wang W, Peng Y, Wang Z. A review on ammonia-hydrogen fueled internal combustion engines. eTransportation. 2023;18:100288. https://doi.org/10.1016/j.etra....
52.
Quiros DC, Smith J, Thiruvengadam A, Huai T, Hu S. Greenhouse gas emissions from heavy-duty natural gas, hybrid, and conventional diesel on-road trucks during freight transport. Atmos Environ. 2017;168:36-45. https://doi.org/10.1016/j.atmo....
53.
Ramasamy D, Kadirgama K, Rahman MM, Zainal ZA. Analysis of compressed natural gas burn rate and flame propagation on a sub-compact vehicle engine. Int J Automot Mech Eng. 2015;11:2405-2416. https://doi.org/10.15282/ijame.... 2015.21.0202.
54.
Reiter AJ, Kong S-C. Demonstration of compression-ignition engine combustion using ammonia in reducing greenhouse gas emissions. Energy Fuels. 2008;22(5):2963-2971. https://doi.org/10.1021/ef8001....
55.
Ryu K. Zacharakis-Jutz GE, Kong S, Effects of gaseous ammonia direct injection on performance characteristics of a spark-ignition engine. Appl Energ. 2014;116:206-215. https://doi.org/10.1016/j.apen....
56.
Ryu K, Zacharakis-Jutz GE, Kong S-C. Performance characteristics of compression-ignition engine using high concentration of ammonia mixed with dimethyl ether. Appl Energ. 2014;113:488-499. https://doi.org/10.1016/j.apen....
57.
Schneider T. It is critical to find alternative low- or no-emission solutions. MTZ Worldwide. 2023;84(1):24-27. https://doi.org/10.1007/s38313....
58.
Seba B, Gobin P. Towards zero emissions solution with hydrogen and ammonia combustion engines. Aachen Colloquium Sustainable Mobility. 2024.
59.
Shen Y, Zhang K, Duwig C. Investigation of wet ammonia combustion characteristics using LES with finite-rate chemistry. Fuel. 2021;311:122422. https://doi.org/10.1016/j.fuel....
60.
Shrestha KP, Giri BR, Elbaz AM, Issayev G, Roberts WL, Seidel L et al. A detailed chemical insights into the kinetics of diethyl ether enhancing ammonia combustion and the importance of NOx recycling mechanism. Fuel Communication. 2022;10:100051. https://doi.org/10.1016/j.jfue....
61.
Starkman E, James G, Newhall H. Ammonia as a diesel engine fuel: theory and application. SAE Technical Paper. 670946, 1967. https://doi.org/10.4271/670946.
62.
Stępień Z. Specificity of lubricants for electric car powertrains. Nafta-Gaz. 2023;2:131-140. https://doi.org/10.18668/NG.20....
63.
Stępień Z. Dywersyfikacja zespołów napędowych i paliw – wyzwania dla silnikowych olejów smarowych (in Polish). Nafta-Gaz. 2024;1:45-54. https://doi.org/10.18668/NG.20....
64.
Stępień Z. Analysis of the prospects for hydrogen-fuelled internal combustion engines. Combustion Engines. 2024;197(2):32-41. https://doi.org/10.19206/CE-17....
65.
Stępień Z. Synthetic automotive fuels. Combustion Engines. 2023;192(1):78-90. https://doi.org/10.19206/CE-15....
66.
Swift E, Kane S, Northrop WF. Operating range and emissions from ammonia hydrogen mixtures in spark-ignited engines. ASME 2022 ICE Forward Conference ICEF2022-91825;2022. https://doi.org/10.1115/ICEF20....
67.
Tay KL, Yang W, Chou SK, Zhou D, Li J, Yu W et al. Effects of injection timing and pilot fuel on the combustion of a kerosene-diesel/ammonia dual fuel engine: a numerical study. Enrgy Proced. 2017;105:4621-4626. https://doi.org/10.1016/j.egyp....
68.
Tornatore C, Marchitto L, Sabia P, De Joannon M. Ammonia as green fuel in internal combustion engines: state-of-the-art and future perspectives. Frontiers in Mechanical Engineering. 2022;8:1-16. https://doi.org/10.3389/fmech.....
69.
Toyota, Asian Industries, (2010): Ammonia burning internal combustion engine. Patent EP 2378105 A, EP 2 378 094 A1.
70.
Van Blarigan P. Advanced internal combustion electrical generator. 2001. DOE Hydrogen Program Review NREL/CP-570-30535. https://www1.eere.energy.gov/h....
71.
Valera-Medina A, Amer-Hatem F, Azad A, Dedoussi I, De Joannon M, Fernandes R et al. Review on ammonia as a potential fuel: from synthesis to economics. Energy Fuels. 2021;35(9):6964-7029. https://doi.org/10.1021/acs.en....
72.
Verkamp FJ, Hardin MC, Williams JR. Ammonia combustion properties and performance in gas-turbine burners. Symposium (International) on Combustion. 1967;11(1):985-992. https://doi.org/10.1016/S0082-....
73.
Wabel TM, Skiba AW, Temme JE, Driscoll JF. Measurements to determine the regimes of premixed flames in extreme turbulence. Proc Combust Inst. 2017;36(2):1809-1816. https://doi.org/10.1016/j.proc....
74.
Wang F, He G, Zhang B, Chen M, Chen X, Zhang C et al. Insights into the activation effect of H2 pretreatment on Ag/Al2O3 catalyst for the selective oxidation of ammonia. ACS Catal. 2019;9(2):1437-1445. https://doi.org/10.1021/acscat....
75.
Wang H, Murayama T, Lin M, Sakaguchi N, Haruta M, Miura H et al. Understanding the distinct effects of Ag nanoparticles and highly dispersed Ag species on N2 selectivity in NH3-SCO reaction. ACS Catal. 2022;12(10):6108-6118. https://doi.org/10.1021/acscat....
76.
Wermuth N, Gumhold C, Wimmer A, Url M. Laiminger S. The ammonia combustion engine for future power generation applications. Energy Technol. 2023;2301008. https://doi.org/10.1002/ente.2....
77.
Westlye FR, Ivarsson A, Schramm J. Experimental investigation of nitrogen based emissions from an ammonia fueled SI-engine. Fuel. 2013;111:239-247. https://doi.org/10.1016/j.fuel....
78.
Wiseman S, Rieth M, Gruberet A, dawson JR, Chen JH. A comparison of the blow-out behavior of turbulent premixed ammonia/hydrogen/nitrogen-air and methane-air flames. Proc Combust Inst. 2021;38(2):2869-2876. https://doi.org/10.1016/j.proc....
79.
Xiao H, Valera-Medina A. Chemical kinetic mechanism study on premixed combustion of ammonia/hydrogen fuels for gas turbine use. J Eng Gas Turbines Power. 2017;8:139. https://doi.org/10.1115/1.4035....
80.
Yapicioglu A, Dincer I. Experimental investigation and evaluation of using ammonia and gasoline fuel blends for power generators. Appl Therm Eng. 2019;154:1-8. https://doi.org/10.1016/j.appl....
81.
Zhang M, An ZA, Wang L, Wei X, Jianayihan B, Wang J et al. The regulation effect of methane and hydrogen on the emission characteristics of ammonia/air combustion in a model combustor. Int J Hydrogen Energ. 2021;46(40):21013-21025. https://doi.org/10.1016/j.ijhy....
82.
Zhu D, Shu B. Recent progress on combustion characteristics of ammonia-based fuel blends and their potential in internal combustion engines. International Journal of Automotive Manufacturing and Materials. 2023;2(1):1. https://doi.org/10.53941/ijamm....
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